Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines
Autor: | Fernando P. Cossío, Abel de Cózar, Miguel A. Sierra, Luis Casarrubios, Jaime G. Muntaner, Bimal K. Banik, Debasish Bandyopadhyay |
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Rok vydání: | 2022 |
Předmět: | |
Zdroj: | RSC Advances. 12:104-117 |
ISSN: | 2046-2069 |
DOI: | 10.1039/d1ra06114c |
Popis: | Computational-experimental analysis has allowed determining that the stereochemistry of the Staudinger reaction between ketenes and imines is strongly associated with the nature of the imine, which affects the two steps of the reaction. The first step, namely the nucleophilic attack of the sp |
Databáze: | OpenAIRE |
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