Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines

Autor: Fernando P. Cossío, Abel de Cózar, Miguel A. Sierra, Luis Casarrubios, Jaime G. Muntaner, Bimal K. Banik, Debasish Bandyopadhyay
Rok vydání: 2022
Předmět:
Zdroj: RSC Advances. 12:104-117
ISSN: 2046-2069
DOI: 10.1039/d1ra06114c
Popis: Computational-experimental analysis has allowed determining that the stereochemistry of the Staudinger reaction between ketenes and imines is strongly associated with the nature of the imine, which affects the two steps of the reaction. The first step, namely the nucleophilic attack of the sp
Databáze: OpenAIRE