Meyer-Schuster-Type Rearrangement of Propargylic Alcohols into α-Selenoenals and -enones with Diselenides

Autor:	Fei-Cen Ma, Long You, Kai-Wen Feng, Xiao-Ling Jin, Yong-Liang Ban, Qiang Liu
Rok vydání:	2021
Předmět:	010405 organic chemistry Chemistry Organic Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences
Zdroj:	The Journal of organic chemistry. 86(7)
ISSN:	1520-6904
Popis:	We describe a mild and broadly applicable protocol for the preparation of a diverse array of multisubstituted α-selenoenals and -enones from readily accessible propargylic alcohols and diselenides. The transformation proceeds via the Selectfluor-promoted selenirenium pathway, which enables selenenylation/rearrangement of a variety of propargylic alcohols. Gram-scale experiments showed the potential of this synergistic protocol for practical application.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::89768a90021741859a3ec8d818697855 https://pubmed.ncbi.nlm.nih.gov/33709711 Zobrazit plný text záznamu