| Autor: |
Fei-Cen Ma, Long You, Kai-Wen Feng, Xiao-Ling Jin, Yong-Liang Ban, Qiang Liu |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
The Journal of organic chemistry. 86(7) |
| ISSN: |
1520-6904 |
| Popis: |
We describe a mild and broadly applicable protocol for the preparation of a diverse array of multisubstituted α-selenoenals and -enones from readily accessible propargylic alcohols and diselenides. The transformation proceeds via the Selectfluor-promoted selenirenium pathway, which enables selenenylation/rearrangement of a variety of propargylic alcohols. Gram-scale experiments showed the potential of this synergistic protocol for practical application. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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