Chemoselective Aerobic Cross-Dehydrogenative Coupling of Terminal Alkynes with Hydrosilanes by a Nanoporous Gold Catalyst

Autor:	Indra Kusuma, Yoshifumi Ishikawa, Rahul D. Kavthe, Naoki Asao
Rok vydání:	2018
Předmět:	Silylation 010405 organic chemistry Nanoporous Chemistry Organic Chemistry General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Coupling (electronics) Terminal (electronics)
Zdroj:	Chemistry - A European Journal. 24:15777-15780
ISSN:	0947-6539
DOI:	10.1002/chem.201803874
Popis:	Aerobic cross-dehydrogenative coupling between terminal alkynes and hydrosilanes occurred in the presence of nanoporous gold catalyst under O2 atmosphere. A variety of alkynylsilanes were synthesized in good-to-high yields and the catalyst was easily recovered and reused many times. Furthermore, the chemoselective direct silyl protection of terminal acetylenes of alkynols over the hydroxyl groups was achieved with this catalytic system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::84506beb020a90ae3218a96d63773e2e https://doi.org/10.1002/chem.201803874 Zobrazit plný text záznamu Plný text ve formátu PDF