| Autor: |
Indra Kusuma, Yoshifumi Ishikawa, Rahul D. Kavthe, Naoki Asao |
| Rok vydání: |
2018 |
| Předmět: |
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| Zdroj: |
Chemistry - A European Journal. 24:15777-15780 |
| ISSN: |
0947-6539 |
| DOI: |
10.1002/chem.201803874 |
| Popis: |
Aerobic cross-dehydrogenative coupling between terminal alkynes and hydrosilanes occurred in the presence of nanoporous gold catalyst under O2 atmosphere. A variety of alkynylsilanes were synthesized in good-to-high yields and the catalyst was easily recovered and reused many times. Furthermore, the chemoselective direct silyl protection of terminal acetylenes of alkynols over the hydroxyl groups was achieved with this catalytic system. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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