| Autor: |
Chia-Chung Tsai, Chi-Hui Tsai, Tu-Hsin Yan, Ching-Ting Chien, Ying-Chuan Wang, Ping-Kuei Tsai, Tsai-Yuan Chang |
| Rok vydání: |
2006 |
| Předmět: |
|
| Zdroj: |
The Journal of organic chemistry. 71(11) |
| ISSN: |
0022-3263 |
| Popis: |
The Ti−Mg−dichloromethylene complexes derived from the oxidative addition of CCl4 to the Mg−TiCl4 bimetallic species serve as a novel class of ambiphilic dichlorocarbenoid equivalents. Not only is Ti−Mg−dichlorocarbenoid highly selective but also it seems highly reactive in both alkene cyclopropanations and carbonyl dichloromethylenations. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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