Novel ambiphilic dichlorocarbenoid equivalent in alkene cyclopropanation and carbonyl olefination

Autor:	Chia-Chung Tsai, Chi-Hui Tsai, Tu-Hsin Yan, Ching-Ting Chien, Ying-Chuan Wang, Ping-Kuei Tsai, Tsai-Yuan Chang
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Ketone chemistry Alkene Cyclopropanation Organic Chemistry Organic chemistry General Medicine Selectivity Highly selective Combinatorial chemistry Bimetallic strip Oxidative addition
Zdroj:	The Journal of organic chemistry. 71(11)
ISSN:	0022-3263
Popis:	The Ti−Mg−dichloromethylene complexes derived from the oxidative addition of CCl4 to the Mg−TiCl4 bimetallic species serve as a novel class of ambiphilic dichlorocarbenoid equivalents. Not only is Ti−Mg−dichlorocarbenoid highly selective but also it seems highly reactive in both alkene cyclopropanations and carbonyl dichloromethylenations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c7eb6319f11717dac0574f58638e07e https://pubmed.ncbi.nlm.nih.gov/16709081 Zobrazit plný text záznamu