Hydrocarbon radiolysis in the presence of carboranes(12) 3. Formation of product hydrocarbons
Autor: | D. M. Mikhailov, G. G. Kakabekov, V. O. Meintser, M. F. Romantsev, M. E. Kuimova, T. Ya. Livertovskaya |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:1383-1387 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00928510 |
Popis: | A study has been made of the effect of o-carborane on hydrocarbon formation in the radiolysis of n-heptane. The introduction of o-carborane into the n-heptane system reduced the yield of “intermediate” and dimeric hydrocarbon products. The inhibiting effect of o-carborane traces back to its electron-acceptor activity and its ability to deactivate the excited n-heptane molecule. |
Databáze: | OpenAIRE |
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