Hydrocarbon radiolysis in the presence of carboranes(12) 3. Formation of product hydrocarbons

Autor: D. M. Mikhailov, G. G. Kakabekov, V. O. Meintser, M. F. Romantsev, M. E. Kuimova, T. Ya. Livertovskaya
Rok vydání: 1977
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:1383-1387
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00928510
Popis: A study has been made of the effect of o-carborane on hydrocarbon formation in the radiolysis of n-heptane. The introduction of o-carborane into the n-heptane system reduced the yield of “intermediate” and dimeric hydrocarbon products. The inhibiting effect of o-carborane traces back to its electron-acceptor activity and its ability to deactivate the excited n-heptane molecule.
Databáze: OpenAIRE