ChemInform Abstract: Synthesis of New Trialkylsilylmethyloxazinones via Intramolecular Trapping of β-Silyl Carbocations by an N-Boc Group
Autor: | H. Dhimane, Gérard Lhommet, Jean-Christophe Poupon, Sylvie Brocherieux-Lanoy, C. Vanucci |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 28 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.199749175 |
Popis: | N -Boc amino ethers 1a–e when treated with allyltrialkylsilanes in the presence of TiCl4 afford the expected allylation compounds 2a–e and/or the unprecedented silylated oxazinones 3a–e or 4a–e. |
Databáze: | OpenAIRE |
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