ChemInform Abstract: Synthesis of New Trialkylsilylmethyloxazinones via Intramolecular Trapping of β-Silyl Carbocations by an N-Boc Group

Autor: H. Dhimane, Gérard Lhommet, Jean-Christophe Poupon, Sylvie Brocherieux-Lanoy, C. Vanucci
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 28
ISSN: 0931-7597
DOI: 10.1002/chin.199749175
Popis: N -Boc amino ethers 1a–e when treated with allyltrialkylsilanes in the presence of TiCl4 afford the expected allylation compounds 2a–e and/or the unprecedented silylated oxazinones 3a–e or 4a–e.
Databáze: OpenAIRE