Flash Photolysis Studies of the Ruthenium(II) Porphyrins Ru(P)(NO)(ONO). Multiple Pathways Involving Reactions of Intermediates with Nitric Oxide1
Autor: | Peter C. Ford, Brian Lee, Jon R. Schoonover, Stefan Bernhard, Katrina M. Miranda, Ivan M. Lorkovic |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Journal of the American Chemical Society. 120:11674-11683 |
ISSN: | 1520-5126 0002-7863 |
DOI: | 10.1021/ja981907o |
Popis: | Described are the spectra and kinetics of transients formed by laser flash photolysis of the ruthenium nitrosyl nitrito complexes Ru(P)(NO)(ONO), P = TPP (meso-tetraphenylporphyrin), OEP (octaethylporphyrin), TmTP (tetra(m-tolyl)porphyrin), and FTTP (tetra(m-trifluoromethylphenyl)porphyrin) in benzene solutions. Two transient decay processes are seen on the time frame ( |
Databáze: | OpenAIRE |
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