Flash Photolysis Studies of the Ruthenium(II) Porphyrins Ru(P)(NO)(ONO). Multiple Pathways Involving Reactions of Intermediates with Nitric Oxide1

Autor: Peter C. Ford, Brian Lee, Jon R. Schoonover, Stefan Bernhard, Katrina M. Miranda, Ivan M. Lorkovic
Rok vydání: 1998
Předmět:
Zdroj: Journal of the American Chemical Society. 120:11674-11683
ISSN: 1520-5126
0002-7863
DOI: 10.1021/ja981907o
Popis: Described are the spectra and kinetics of transients formed by laser flash photolysis of the ruthenium nitrosyl nitrito complexes Ru(P)(NO)(ONO), P = TPP (meso-tetraphenylporphyrin), OEP (octaethylporphyrin), TmTP (tetra(m-tolyl)porphyrin), and FTTP (tetra(m-trifluoromethylphenyl)porphyrin) in benzene solutions. Two transient decay processes are seen on the time frame (
Databáze: OpenAIRE