Popis: |
Computer deconvolution of spectra is discussed, and a close comparison made of deconvoluted spectra with those measured at higher resolution. It is shown that spectra at a resolution of ∼0.012 cm−1 can be obtained by the use of a relatively small grating spectrometer. The parallel band, ν9 + ν10, of C2D6 is examined at a resolution of 0.012 cm−1 but no K-structure is observed, indicating that (A′−B′)−(A″−B″) is less than 1 × 10−5 cm−1. Rotational constants are given for the main band and two hot bands. |