Computer deconvolution applied to the parallel band, ν9 + ν10, of hexadeuteroethane

Autor: A.R.H. Cole, K.G. May
Rok vydání: 1982
Předmět:
Zdroj: Journal of Molecular Structure. 80:15-21
ISSN: 0022-2860
DOI: 10.1016/0022-2860(82)87202-5
Popis: Computer deconvolution of spectra is discussed, and a close comparison made of deconvoluted spectra with those measured at higher resolution. It is shown that spectra at a resolution of ∼0.012 cm−1 can be obtained by the use of a relatively small grating spectrometer. The parallel band, ν9 + ν10, of C2D6 is examined at a resolution of 0.012 cm−1 but no K-structure is observed, indicating that (A′−B′)−(A″−B″) is less than 1 × 10−5 cm−1. Rotational constants are given for the main band and two hot bands.
Databáze: OpenAIRE