Kinetics and mechanism of the aminolysis of 2,4-dinitrophenyl and 2,4,6-trinitrophenyl O-ethyl dithiocarbonates

Autor:	Mirtha Salas, Fernando Ibanez, Enrique A. Castro, José G. Santos, Patricia Sepulveda
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Alicyclic compound Aminolysis Reaction rate constant chemistry Ionic strength Organic Chemistry Kinetics Nitro compound Organic chemistry Substrate (chemistry) Amine gas treating Medicinal chemistry
Zdroj:	The Journal of Organic Chemistry. 58:459-463
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00054a033
Popis:	The reactions of a series of secondary alicyclic amines with the title substrates (DNPDTC and TNPDTC) are subject to a kinetic study in water at 25.0 o C, ionic strength 0.2 M (KCl). The reactions are first order in both the amine and the substrate. The Bronsted-type plots obtained are nonlinear and are explained by a stepwise mechanism through a zwitterionictetrahedral intermediate (T ± ), although a concerted process is not rigorously excluded for the reactions of the less basic amines with TNPDTC
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9ee4bdc883482575995cb6e01d6a5ffb https://doi.org/10.1021/jo00054a033 Zobrazit plný text záznamu