An extreme case of ZnO6octahedral distortion in trizinc tris(selenite) hydrate, Zn3(SeO3)3

Autor:	W. T. A. Harrison
Rok vydání:	1999
Předmět:	Tris chemistry.chemical_element General Medicine Crystal structure Zinc General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography Octahedron chemistry Hydrothermal synthesis Isostructural Hydrate Selenium
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 55:1980-1983
ISSN:	0108-2701
DOI:	10.1107/s0108270199011099
Popis:	Trizinc tris[trioxoselenate(IV)] hydrate, Zn 3 (SeO 3 ) 3 .H 2 O, is built up from ZnO 6 octahedra [d av (Zn-O) = 2.127 (2) A] and SeO 3 pyramids [d av (Se-O) = 1.693 (2) A], sharing vertices and edges. One of the zinc octahedra is exceptionally distorted. The title compound is isostructural with Co 3 (SeO 3 ) 3 .H 2 O and Ni 3 (SeO 3 ) 3 .H 2 O.
Databáze:	OpenAIRE
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