Initiation of high-temperature reaction of tetrachloroethylene with methyl alcohol

Autor:	L. P. Gudovich, M. A. Besprozvannyi, Yu. B. Vol'kenshtein, L. K. Salamandra, G. I. Nikishin
Rok vydání:	1972
Předmět:	Inert chemistry.chemical_compound Chemistry Molar ratio Yield (chemistry) Tetrachloroethylene Condensation Inorganic chemistry Tar Alcohol General Chemistry Methanol Photochemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 21:2532-2534
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00850114
Popis:	1. The high-temperature condensation of tetrachloroethylene with methanol is initiated by polychloroorganic and carbonyl compounds. 2. The addition of initiators and an optimization of the process make it possible to lower the reaction temperature by 100° and obtain the same yield of trichloroallyl alcohol, decrease the molar ratio of the reactants by half, and increase the output of the reactor by 25–30%. 3. The use of an inert packing reduces the losses of tetrachloroethylene for tar formation by a matter of 2–3 times.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b8562b6c4d4df55a437d0d3f7208752 https://doi.org/10.1007/bf00850114 Zobrazit plný text záznamu Full text from SpringerLink