Synthesis and characterization of the chiral iron secondary methoxycarbene [Fe(C5Me5)(CO)(PMePh2)(CHOMe)][SO3CF3]

Autor:	Véronique Guerchais, Marie-José Tudoret, Claude Lapinte
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Stereochemistry Organic Chemistry Salt (chemistry) Alkylation Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry Methylene Carbene
Zdroj:	Journal of Organometallic Chemistry. 414:373-380
ISSN:	0022-328X
DOI:	10.1016/0022-328x(91)86335-n
Popis:	The chiral iron secondary methoxycarbene [Fe(C 5 Me 5 )(CO)(PMePh 2 )(CHOMe)][SO 3 CF 3 ]( 10 can be conveniently made by direct O -alkylation of the isolated neutral iron formly Fe(C 5 Me 5 )(CO)(PMePh 2 )-(CHO) ( 9 ). This procedure appears efficient to prepare 10 , since the trityl salt [Ph 3 C][PF 6 ] reacts with the methoxymethyl complex Fe(C 5 Me 5 )(CO)(PPh 3 )(CH 2 OMe) ( 2 ) to give the thermally unstable methylene complex [Fe(C 5 Me 5 )(CO)(PPh 3 )(CH 2 )][PF 6 ] ( 4 ).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9b4b42a2546023e290f343b3708b31f9 https://doi.org/10.1016/0022-328x(91)86335-n Zobrazit plný text záznamu