Diels-Alder reactions in chloroaluminate ionic liquids: acceleration and selectivity enhancement

Autor:	Carlos W. Lee
Rok vydání:	1999
Předmět:	Cyclopentadiene Organic Chemistry Photochemistry Biochemistry Chloride Catalysis Solvent chemistry.chemical_compound chemistry Drug Discovery Ionic liquid Diels alder medicine Organic chemistry Methyl acrylate Selectivity medicine.drug
Zdroj:	Tetrahedron Letters. 40:2461-2464
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(99)00249-x
Popis:	The utility of room temperature chloroaluminate ionic liquids as solvent and catalyst for the synthetically important Diels-Alder reaction was studied. The AlCl3-1-ethyl-3-methyl-1H-imidazolium chloride medium proved to be ideally suited for Diels-Alder reactions. Endo selectivity and rate enhancement were observed for the cyclopentadiene/methyl acrylate Diels-Alder reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::860caa9837b49e90d7e169cca605635a https://doi.org/10.1016/s0040-4039(99)00249-x Zobrazit plný text záznamu Full Text from ScienceDirect