Diels-Alder reactions in chloroaluminate ionic liquids: acceleration and selectivity enhancement

Autor: Carlos W. Lee
Rok vydání: 1999
Předmět:
Zdroj: Tetrahedron Letters. 40:2461-2464
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00249-x
Popis: The utility of room temperature chloroaluminate ionic liquids as solvent and catalyst for the synthetically important Diels-Alder reaction was studied. The AlCl3-1-ethyl-3-methyl-1H-imidazolium chloride medium proved to be ideally suited for Diels-Alder reactions. Endo selectivity and rate enhancement were observed for the cyclopentadiene/methyl acrylate Diels-Alder reaction.
Databáze: OpenAIRE
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