Diels-Alder reactions in chloroaluminate ionic liquids: acceleration and selectivity enhancement
Autor: | Carlos W. Lee |
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Rok vydání: | 1999 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 40:2461-2464 |
ISSN: | 0040-4039 |
DOI: | 10.1016/s0040-4039(99)00249-x |
Popis: | The utility of room temperature chloroaluminate ionic liquids as solvent and catalyst for the synthetically important Diels-Alder reaction was studied. The AlCl3-1-ethyl-3-methyl-1H-imidazolium chloride medium proved to be ideally suited for Diels-Alder reactions. Endo selectivity and rate enhancement were observed for the cyclopentadiene/methyl acrylate Diels-Alder reaction. |
Databáze: | OpenAIRE |
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