ChemInform Abstract: Configurational Assignment of α-Chiral Carboxylic Acids by Complexation to Dimeric Zn-Porphyrin: Host-Guest Structure, Chiral Recognition and Circular Dichroism
Autor: | Gloria Proni, Nazia Q. Quraishi, Nina Berova, Gennaro Pescitelli, Koji Nakanishi, Xuefei Huang |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 33 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.200246027 |
Popis: | A circular dichroic (CD) exciton chirality method based on host–guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an α-stereogenic center; an amide C=O→Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation. |
Databáze: | OpenAIRE |
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