ChemInform Abstract: Configurational Assignment of α-Chiral Carboxylic Acids by Complexation to Dimeric Zn-Porphyrin: Host-Guest Structure, Chiral Recognition and Circular Dichroism

Autor: Gloria Proni, Nazia Q. Quraishi, Nina Berova, Gennaro Pescitelli, Koji Nakanishi, Xuefei Huang
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 33
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200246027
Popis: A circular dichroic (CD) exciton chirality method based on host–guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an α-stereogenic center; an amide C=O→Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation.
Databáze: OpenAIRE