First optically active P-alkoxy derivative of palladated phosphacymantrene: synthesis, structure, and chiroptical properties

Autor:	A. G. Ginzburg, K. K. Babievsky, Fedor M. Dolgushin, Pavel V. Petrovskii, Alexander F. Smol'yakov, V. V. Bashilov, Viatcheslav I. Sokolov
Rok vydání:	2013
Předmět:	Diffraction chemistry.chemical_compound Crystallography Circular dichroism Uv spectra chemistry Stereochemistry Alkoxy group General Chemistry Optically active Derivative (chemistry)
Zdroj:	Russian Chemical Bulletin. 62:1080-1085
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-013-0145-7
Popis:	The solvopalladation reaction of 2,5-diphenylphosphacymantrene with Na2PdCl4, AcONa, and optically active carbinol (S)-(−)-2-methylbutanol was carried out. Optically active complex 3 was obtained and characterized by X-ray diffraction analysis and circular dichroism (CD), 13C and 31P NMR, IR, and UV spectra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5e38ef26b69d6b23b09f52341d74295e https://doi.org/10.1007/s11172-013-0145-7 Zobrazit plný text záznamu Full text from SpringerLink