First optically active P-alkoxy derivative of palladated phosphacymantrene: synthesis, structure, and chiroptical properties

Autor: A. G. Ginzburg, K. K. Babievsky, Fedor M. Dolgushin, Pavel V. Petrovskii, Alexander F. Smol'yakov, V. V. Bashilov, Viatcheslav I. Sokolov
Rok vydání: 2013
Předmět:
Zdroj: Russian Chemical Bulletin. 62:1080-1085
ISSN: 1573-9171
1066-5285
DOI: 10.1007/s11172-013-0145-7
Popis: The solvopalladation reaction of 2,5-diphenylphosphacymantrene with Na2PdCl4, AcONa, and optically active carbinol (S)-(−)-2-methylbutanol was carried out. Optically active complex 3 was obtained and characterized by X-ray diffraction analysis and circular dichroism (CD), 13C and 31P NMR, IR, and UV spectra.
Databáze: OpenAIRE
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