Structural features of compounds of the sillenite family

Autor: E. A. Mar’ina, T. I. Mel’nikova, N. V. Sadovskaya, Ya. V. Zubavichus, Nadezhda B. Bolotina, Victor B. Rybakov, Galina M. Kuz’micheva
Rok vydání: 2014
Předmět:
Zdroj: Crystallography Reports. 59:353-361
ISSN: 1562-689X
1063-7745
DOI: 10.1134/s1063774514030134
Popis: It is shown that the real composition and structure of phases belonging to the sillenite family can be determined using a complex of techniques (diffraction methods, vibrational and X-ray absorption spectroscopy, and electron probe X-ray microanalysis) with a subsequent crystal-chemical analysis of the data. Refined compositions are presented for phases of nominal composition Bi24M2O40 with M = Zn2+, Al3+, Ga3+, Fe3+, Si4+, Ti4+, Mn4+, and P5+, which demonstrate types and concentrations of point defects as functions of the M type.
Databáze: OpenAIRE