Effect of aromatic ?-substrates on the exchange dynamics of axial ligands in iron(III) porphyrins

Autor:	A. N. Kitaigorodskii, O. A. Chamaeva, S. G. Sakharov
Rok vydání:	1990
Předmět:	Crystallography Chemistry Stereochemistry General Chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:2277-2281
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00958837
Popis:	The effect of aromatic π-substrates on the rate of inversion of Fe3+ in five-coordinate high-spin iron(III) porphyrins has been investigated using PMR. It was shown that π-substrates may influence both associative and dissociative inversion channels; π-donor and π-acceptor effects have opposite signs in the latter case, indicating that the influence of π-substrates acts by an electronic mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::481cdbbca8bb051c6e5c3a454809b909 https://doi.org/10.1007/bf00958837 Zobrazit plný text záznamu Full text from SpringerLink