Formation of organometallic compounds of carbene and carbine types by the interaction of RLi with neodymium and yttrium chlorides in various media
| Autor: | I. Sh. Guzman, E. I. Tinyakova, N.N. Chigir, E.L. Vollerstein, B. A. Dolgoplosk, V. A. Yakovlev, Galina N. Bondarenko, O. K. Sharaev |
|---|---|
| Rok vydání: | 1980 |
| Předmět: |
chemistry.chemical_classification
Organic Chemistry chemistry.chemical_element Yttrium Photochemistry Biochemistry Medicinal chemistry Neodymium Inorganic Chemistry Metal chemistry.chemical_compound Hydrocarbon chemistry visual_art Atom Materials Chemistry visual_art.visual_art_medium Carbine Physical and Theoretical Chemistry Carbene Group 2 organometallic chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 201:249-255 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)92580-4 |
| Popis: | It has been established that in the interaction of NdCl 3 and YCl 3 with RLi, where R CH 2 C 6 H 5 , CH 2 C(CH 3 ) 2 C 6 H 5 , CH 2 Si(CH 3 ) 3 , unusual organometallic compounds are formed. They are stable in hydrocarbon solutions. The benzyl and neophyl derivatives are carbene type complexes containing one R group at a trivalent metal atom. In all cases the reaction is accompanied by the evolution of RH as the main product and some stilbene and tolan when R CH 2 C 6 H 5 . The mechanism of this reaction is discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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