ChemInform Abstract: SOME STABLE SUBSTITUTED CYCLOHEPTATRIENYL CARBANIONS
Autor: | A. W. Zwaard, H. Kloosterziel |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Chemischer Informationsdienst. 12 |
ISSN: | 0009-2975 |
DOI: | 10.1002/chin.198125184 |
Popis: | The reaction of some 7-substituted cycloheptatrienes with KNH2 in liquid ammonia is described. In several cases stable carbanions are formed. Their NMR spectra are consistent with a non-planar pentadienyl-like structure. A comparison of the 1H-NMR spectra of 10 and 11 shows the paratropic character of the cycloheptatrienyl anions. |
Databáze: | OpenAIRE |
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