ChemInform Abstract: SOME STABLE SUBSTITUTED CYCLOHEPTATRIENYL CARBANIONS

Autor: A. W. Zwaard, H. Kloosterziel
Rok vydání: 1981
Předmět:
Zdroj: Chemischer Informationsdienst. 12
ISSN: 0009-2975
DOI: 10.1002/chin.198125184
Popis: The reaction of some 7-substituted cycloheptatrienes with KNH2 in liquid ammonia is described. In several cases stable carbanions are formed. Their NMR spectra are consistent with a non-planar pentadienyl-like structure. A comparison of the 1H-NMR spectra of 10 and 11 shows the paratropic character of the cycloheptatrienyl anions.
Databáze: OpenAIRE