Infrared and Raman spectra of [(CH3)3C]2PF and [(CH3)3C]2PCl

Autor: G. Ting-Kuo Fey, Robert R. Holmes, Robert H. Larkin
Rok vydání: 1973
Předmět:
Zdroj: Spectrochimica Acta Part A: Molecular Spectroscopy. 29:665-673
ISSN: 0584-8539
DOI: 10.1016/0584-8539(73)80096-0
Popis: The liquid state infrared spectra of bis(t-butyl) fluorophosphine and bis(t-butyl) chlorophosphine were recorded from 3100 to 33 cm−1. Corresponding Raman displacements are reported as well as polarization data. Assignments of fundamental frequencies are consistent with Cs symmetry for the skeletal framework and local C3v for the t-butyl groups. The assignments are compared with those of the related t-butyl-dihalophosphines reported earlier.
Databáze: OpenAIRE