Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates

Autor:	Suk-Ku Kang, Ryung-Kee Hong, Pil-Su Ho, Dae-Yeun Kim
Rok vydání:	1996
Předmět:	chemistry.chemical_compound Allylic rearrangement chemistry Nucleophile Organic Chemistry Substitution (logic) chemistry.chemical_element Alcohol Combinatorial chemistry Medicinal chemistry Catalysis Ruthenium
Zdroj:	Synthetic Communications. 26:3225-3235
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919608004631
Popis:	Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh3)2Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-allyl ruthenium complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::24340190e779c9d4eeefd536b55b6257 https://doi.org/10.1080/00397919608004631 Zobrazit plný text záznamu