Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates

Autor: Suk-Ku Kang, Ryung-Kee Hong, Pil-Su Ho, Dae-Yeun Kim
Rok vydání: 1996
Předmět:
Zdroj: Synthetic Communications. 26:3225-3235
ISSN: 1532-2432
0039-7911
Popis: Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh3)2Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-allyl ruthenium complex.
Databáze: OpenAIRE