Piperidine-modified fischer-tropsch synthesis
Autor: | Vladimir G. Zaikin, G. A. Kliger, O.A. Lesik, Mikaya Anzor I, Glebov Leonid S, S. M. Loktev, E. V. Marchevskaya |
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Rok vydání: | 1991 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:435-438 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00965446 |
Popis: | N-Alkylpiperidines with alkyl fragment length from C1 to Cl5 were synthesized by the reaction of CO + H2 + piperidine. The molecular mass distribution of the N-alkylpiperidines has two different distribution parameters α. Thus, α=0.45±0.03 for C1-C5 alkyl fragments, while α=0.65±0.02 for C6-C15. Piperidine was found to act as a modifier reagent and chemical trap for the intermediates in the synthesis reaction. |
Databáze: | OpenAIRE |
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