Piperidine-modified fischer-tropsch synthesis

Autor: Vladimir G. Zaikin, G. A. Kliger, O.A. Lesik, Mikaya Anzor I, Glebov Leonid S, S. M. Loktev, E. V. Marchevskaya
Rok vydání: 1991
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:435-438
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00965446
Popis: N-Alkylpiperidines with alkyl fragment length from C1 to Cl5 were synthesized by the reaction of CO + H2 + piperidine. The molecular mass distribution of the N-alkylpiperidines has two different distribution parameters α. Thus, α=0.45±0.03 for C1-C5 alkyl fragments, while α=0.65±0.02 for C6-C15. Piperidine was found to act as a modifier reagent and chemical trap for the intermediates in the synthesis reaction.
Databáze: OpenAIRE