Z,E-isomers of 10,10-dimethyl-9-benzylidene-9,10-dihydro-10-sila-2-azaanthracene and reactions of 10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene under conditions of basic catalysis

Autor:	Alexey V. Varlamov, Aa Fomichev, K. Kozm, Ae Aliev, N. S. Prostatkov
Rok vydání:	1987
Předmět:	chemistry.chemical_classification chemistry Stereochemistry Organic Chemistry Cleavage (embryo) Aldehyde Catalysis
Zdroj:	Chemistry of Heterocyclic Compounds. 23:1136-1140
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00476548
Popis:	The synthesis of 9-benzylidenesilaazaanthracenes has been achieved, and the configurations of their Z- and E-isomers have been established. The reactions of silaazaanthracene in the presence of aromatic aldehydes and bases have been studied; these result in dimerization, oxidation, cleavage of the Si-C bond, and desilylation of the heterocyclic system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::035a2a8bd9fca1e18ca6595f7864af23 https://doi.org/10.1007/bf00476548 Zobrazit plný text záznamu Full text from SpringerLink