Z,E-isomers of 10,10-dimethyl-9-benzylidene-9,10-dihydro-10-sila-2-azaanthracene and reactions of 10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene under conditions of basic catalysis
Autor: | Alexey V. Varlamov, Aa Fomichev, K. Kozm, Ae Aliev, N. S. Prostatkov |
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Rok vydání: | 1987 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 23:1136-1140 |
ISSN: | 1573-8353 0009-3122 |
DOI: | 10.1007/bf00476548 |
Popis: | The synthesis of 9-benzylidenesilaazaanthracenes has been achieved, and the configurations of their Z- and E-isomers have been established. The reactions of silaazaanthracene in the presence of aromatic aldehydes and bases have been studied; these result in dimerization, oxidation, cleavage of the Si-C bond, and desilylation of the heterocyclic system. |
Databáze: | OpenAIRE |
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