Thermal decomposition of N-fluoroazoxy derivatives

Autor: Grebennikov, V. N., Manelis, G. B., Nazin, G. M., Studnev, Yu. N., Fokin, A. V.
Zdroj: Russian Chemical Bulletin; August 1984, Vol. 33 Issue: 8 p1573-1575, 3p
Abstrakt: The kinetics of the thermal decomposition of 2-nitro- and 2-difluoroamino-2-N-difluoro-azoxypropane, members of the class of N-fluoroazoxyalkanes, were investigated. It was shown that the reaction takes place in the gas phase according to a molecular mechanism through a six-site activated complex. The NF2 group in the a position affects the decomposition of the N-fluoroazoxy group more strongly than NO2.
Databáze: Supplemental Index