Autor: |
Grebennikov, V. N., Manelis, G. B., Nazin, G. M., Studnev, Yu. N., Fokin, A. V. |
Zdroj: |
Russian Chemical Bulletin; August 1984, Vol. 33 Issue: 8 p1573-1575, 3p |
Abstrakt: |
The kinetics of the thermal decomposition of 2-nitro- and 2-difluoroamino-2-N-difluoro-azoxypropane, members of the class of N-fluoroazoxyalkanes, were investigated. It was shown that the reaction takes place in the gas phase according to a molecular mechanism through a six-site activated complex. The NF2 group in the a position affects the decomposition of the N-fluoroazoxy group more strongly than NO2. |
Databáze: |
Supplemental Index |
Externí odkaz: |
|