Autor: |
Kryuchkov, A. A., Komarova, M. P., Kozachenko, A. G., Matrosov, E. I., Nifant'ev, É. E., Kabachnik, M. I. |
Zdroj: |
Russian Chemical Bulletin; November 1979, Vol. 28 Issue: 11 p2272-2277, 6p |
Abstrakt: |
1.Potentiometric titration, vibrational and NMR spectroscopy were used to study the acid-base properties and hydrolytic stability of pinacone phosphite in different media.2.The proton-acceptor capacity of the phosphoryl group oxygen atom of pinacone phosphite is similar to the proton-acceptor capacity of dialkyl phosphites.3.In water and water-ethanol solutions, pinacone phosphite hydrolyzes with the formation of a phosphorous acid monoester. The hydrolysis of pinacone phosphite is reversible in nature. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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