A New Electrode for Micro-Determination of Paper pH.

Autor: Strlič, Matija1, Pihlar, Boris1, Mauko, Lea1, Kolar, Jana2, Hočevar, Samo3, Ogorevc, Božidar3
Předmět:
Zdroj: Restaurator. 2005, Vol. 26 Issue 3, p159-171. 13p.
Abstrakt: The article focuses on developments of polyaniline-coated glassy carbon electrodes for pH determination of various materials. Polyaniline film was electro-polymerized on a tailor-made flat surface polished glassy carbon electrode of 1-mm diameter in a polytef holder of 1-cm diameter. The electrode was first activates in 0.5 mole per liter hydrochloric acid at 2.0 volt for 30 seconds. After this procedure the potential was cycled five times between -1.1 and +1.6 volt. Afterwards, the solution was exchanged with 0.1 mole per liter aniline in 1 mole per liter hydrochloric acid and the potential cycled 25 times between -0.2 and 1.0 volts using Potentiostat/Galvanostat Model 273.
Databáze: Library, Information Science & Technology Abstracts