Part I. Coordination chemistry of SmI3 with donor solvents: Part II. Synthesis and structural characterization of lanthanacarboranes.

Jazyk: angličtina
Rok vydání: 1997
Předmět:
Druh dokumentu: Bibliografie
Popis: by Ka-yue Chiu.
The "3" in the title is subscript.
Thesis (M.Phil.)--Chinese University of Hong Kong, 1996.
Includes bibliographical references (leaves 103-110).
ACKNOWLEDGEMENTS --- p.3
ABBREVIATIONS --- p.4
p.5
Chapter I. --- COORDINATION CHEMISTRY OF SmI3 WITH DONOR SOLVENTS --- p.7
Chapter 1.1. --- Introduction --- p.7
Chapter 1.2 --- Results and Discussion --- p.21
Chapter 1.2.A --- Synthesis and Structural Characterization of [trans-SmI2(THF)5][trans- SmI4(THF)2] (1) --- p.21
Chapter 1.2.B --- Synthesis and Structural Characterization of SmI3(DME)2 (2) --- p.26
Chapter 1.2.C --- Synthesis and Structural Characterization of [{Sm(H20)3}2{Sm(CH3CN) (H20)3}2{Sm(CH3CN)3(H20)}2(μ3-OH)8(μ6-0)]I8-2H20 (3) --- p.30
Chapter 1.3 --- Conclusion --- p.38
Chapter 1.4 --- Experimental Section --- p.39
Chapter II. --- SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF LANTHANACARBORANES --- p.45
Chapter II.1 --- Introduction --- p.45
Chapter II.2 --- Results and Discussion --- p.51
Chapter II.2.A --- Synthesis and Characterization of closo-Lanthanacarboranes --- p.51
Chapter II.2.A.i --- Sandwich Type Complexes --- p.51
Chapter II.2.A.ii. --- Half-Sandwich Type Complexes --- p.62
Chapter II.2.B --- Synthesis and Characterization of an exo-nido-Samaracarborane --- p.71
Chapter II.2.B.i. --- Synthesis and Characterization of an exo-nido-[{(C6H5CH2)2C2B9H9} Sm(DME)2]2.DME(18) --- p.77
Chapter II.3 --- Conclusion --- p.84
Chapter II.4 --- Experimental Section --- p.85
REFERENCES --- p.99
Databáze: Networked Digital Library of Theses & Dissertations
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