Popis: |
Fuels: Non-renewable fossil fuels are the largest man-made contributor to global warming. Biofuel market share will increase, promoted by renewability, inherent lower net CO\(_2\) emissions, and legislation. The environmental and human health impact of diesel exhaust emission particulate matter (PM) is a major concern. Fossil diesel PM aftertreatment systems exist. Near future fuel PM research and the evaluation of current aftertreatment technology, highlight a route for future development. Using a holistic approach this body of work studies the interdependence between the fuel, the CI engine and associated aftertreatment system. The overall objective of this thesis is the evaluation of current diesel aftertreatment using renewable near future fuels. Diesel blends with 1st and 2nd generation biodiesel fuels are viable. Carefully selected blends like B20G10 can make all round regulated emission improvements. Green additive dimethyl carbonate (DMC) enhances diesel combustion by oxygenation. Regulated emissions of THC, CO (>30% reduced) and PM (50% reduced) for 2% DMC in diesel. 1st generation biodiesel (RME) is widely available. Combustion produces significantly less solid PM than diesel (90% by mass >98% by number, for all fuels. For synthetically produced 2nd generation gas to liquid (GTL) fuels there are potentially DPF regeneration implications. Current aftertreatment solutions are as effective for bio alternatives as they are for fossil diesel. Biodiesels, green additives and aftertreatment are effective clean emissions improvements, until the promise of true zero emission vehicles is realised. |