Synthesis, Structures and properties of Cadmium(Ⅱ) Coordination Polymers Containing Flexible Bis-pyridyl-Bis-amide and Polycarboxylate Ligands
| Autor: | Hui-Ju Lo, 羅惠如 |
|---|---|
| Rok vydání: | 2018 |
| Druh dokumentu: | 學位論文 ; thesis |
| Popis: | 106 Three Cd(II) coordination polymers constructed from flexible bis-pyridyl-bis-amide ligands and dicarboxylic acids with different flexibility, {[Cd(L1)(SA)]．5H2O．CH3OH}n, (L1 = N,N’-di(3-pyridyl)adipoamide ; H2SA = suberic acid), 1, {[Cd(L1)(AA)]．2H2O}n, (H2AA = adipic acid), 2, {[Cd(L2)(SA)]．5H2O．3H2O }n, (L2 = N,N’-di(3-pyridyl)suberoamide), 3, were synthesized by hydrothermal reactions. These complexes were structurally characterized by using single-crystal X-ray diffraction and churactized by using powder X-ray diffraction, Elemental Analyzer and IR spectra. Complexes 1 and 2 and 3 are 2D layers with the sql topologys. Luminiscent and thermal propertties are also discussed. |
| Databáze: | Networked Digital Library of Theses & Dissertations |
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