Development of One-Pot Reactions for Dye-Sensitized and Perovskite Solar Cells via Sequential C-H Arylations.
| Autor: | Kuan-Ming Lu, 盧冠銘 |
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| Rok vydání: | 2017 |
| Druh dokumentu: | 學位論文 ; thesis |
| Popis: | 105 We use 3,4-ethylenedioxythiophene (EDOT), thiophene as middle core and π-linker. In the end groups, we use different donors such as triphenylamine (TPA), carbazole with different alkyl chain to measure their electrochemical, thermal properties, hole mobility and photovoltaic performance. For applications in dye-sensitized solar cells (DSSCs) and perovskite solar cells (PSCs), we demonstrate that two D-A-π-A type new organic sensitizers (CYL-20 and CYL-21) and D-π-D-π-D type hole-transporting materials (KM01-KM07) can be step-economically synthesized by one-pot reactions through sequential C-H arylations. The PCE of perovskite solar cells (PSCs) device achieves 15%. This work aims to provide facile access to high-performance organic sentizers and hole-transporting materials. |
| Databáze: | Networked Digital Library of Theses & Dissertations |
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