1. Microwave-Promoted Rhodium-Catalyzed Carbon-Sulfur Bond Cross-Coupling Reaction In Water2. Yttrium-Catalyzed Carbon-Sulfur Bond Cross-Coupling Reaction
Autor: | Chia-Chen Wu, 吳佳蓁 |
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Rok vydání: | 2014 |
Druh dokumentu: | 學位論文 ; thesis |
Popis: | 102 In the first part of this thesis, we report that a combination of rhodiumsalt with DPPE can be served as a powerful catalyst for microwave-promoted coupling of thiols with iodides in water. The second part of this thesis, we investigate a yttrium-catalyzed cross-coupling reaction of this with aryl iodides by using bathophenanthroline as ligand. Remarkably, it is the first example of yttrium catalyzed C-S bond formation process. |
Databáze: | Networked Digital Library of Theses & Dissertations |
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