1. Microwave-Promoted Rhodium-Catalyzed Carbon-Sulfur Bond Cross-Coupling Reaction In Water2. Yttrium-Catalyzed Carbon-Sulfur Bond Cross-Coupling Reaction

Autor: Chia-Chen Wu, 吳佳蓁
Rok vydání: 2014
Druh dokumentu: 學位論文 ; thesis
Popis: 102
In the first part of this thesis, we report that a combination of rhodiumsalt with DPPE can be served as a powerful catalyst for microwave-promoted coupling of thiols with iodides in water. The second part of this thesis, we investigate a yttrium-catalyzed cross-coupling reaction of this with aryl iodides by using bathophenanthroline as ligand. Remarkably, it is the first example of yttrium catalyzed C-S bond formation process.
Databáze: Networked Digital Library of Theses & Dissertations