Conduction and Electrochemistry Mechanism of Al3+ and Ni2+ doped LiMn2O4 with or without Ball Milling

Autor: Han-Yang Chung, 鍾瀚揚
Rok vydání: 2005
Druh dokumentu: 學位論文 ; thesis
Popis: 93
Decreasing of the temperature causes the phenomenon which the resisitity arise suddenly near temperature 280K. That is the manganese spinel undergoes a phase transition between high -temperature cubic and low temperature orthorhombic phase. Substitution of manganese cause disappearance of the phase transition characteristic of a stoichiometric spinel and affects the conduction mechanism of the material. The powder with ball milling has different electrochemical properties from it with annealing. The material LiMn2O4 doped with Ni2+ or Al3+ ion also shows the different electrochemical properties.
Databáze: Networked Digital Library of Theses & Dissertations