The Photophysical Studies of undecasiliver Clusters Containing Diselenophosphate Ligands
| Autor: | Jui-Chen Fu, 傅瑞珍 |
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| Druh dokumentu: | 學位論文 ; thesis |
| Popis: | 91 In our studies, the reaction of Ag10(Se)[Se2P(OC3H7)2]8 with n-Bu4NX ( X＝I、Br、Cl) affords three kinds of complexes. When X＝I、Br, we obtain Ag11(Se)(X)3[Se2P(OC3H7)2]6; but X＝Cl, we obtain {Ag8(μ8-Se)[Se2P(OC3H7)2]6}0.5{Ag6[Se2P(OC3H7)2]6}0.5. By using 31P NMR, we can observe the transformation of those clusters. Ag8(μ8-Cl)[Se2P(OR)2]6(PF6) ( R＝C2H5、C3H7 ) were obtain from the reaction at the molar ratio of M：L：Cl＝4：3：1 in CH2Cl2 or Ag10(Se)[Se2P(OC3H7)2]8 react with Ag(CH3CN)4(PF6) in CH2Cl2. Because the Ag11(Se)(X)3[Se2P(OR)2]6 ( R＝C2H5、C3H7、C4H9；X＝I、Br) display orange luminescence under UV light, and polynuclear d10 metal complexes always have luminescent properties, hence we present the UV-Vis、excitation and emission spectra of complexes. Preliminary photophysical study will be discussed. |
| Databáze: | Networked Digital Library of Theses & Dissertations |
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