the carbon carbon bond formation of allenyl/Propargrl complexes of palladium and platinum
| Autor: | Sheng Yi CHen, 陳聖宜 |
|---|---|
| Rok vydání: | 1999 |
| Druh dokumentu: | 學位論文 ; thesis |
| Popis: | 87 In Our experiment, we are interested in reaction of η3-Propargyl complexes of platinum and palladium {M(PPh3)2(η3-C3H3)}(BF4), (M = Pd 3, Pt 4 ), with enaminone (NHR)(Me)C=C(COMe)( R = iPr 5a, Me 5b), leads to the formation of the cationic complexes M{η3-CH2 [(COMe)C=C(Me)(NHR)]CH2}(PPh3)2}BF4 (M = Pd 7a 7b, Pt = 8a 8b), via formation of a carbon-carbon bond. After heating the complexes 7,8, the organic compound pyrrole is appeared according to organic ring formation. |
| Databáze: | Networked Digital Library of Theses & Dissertations |
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